PHTHALIC ANHYDRIDE White acicular crystal, flammable, easily sublimed below boiling point, with a slight odor.
| Items | Quality index | Test result |
| Specifications | ||
| Appearance | White flake or
Crystalline powder |
White flake or
Crystalline powder |
| Melting color(PtCo) ≤ | 20 APHA Max | 20 |
| Heating color(PtCo) ≤ | 50 APHA Max | 40 |
| Sulphuric acid colour index ≤ | 40 APHA Max | 10 |
| Solidification point ≥ | 130.5 Degree Min | 131.1 |
| Purity ≥ | 99.5% Min | 99.96 |
| Free acid ≤ | 0.2% Max | 0.06 |
Applications of Phthalic Anhydride
Phthalic anhydride’s dual carbonyl groups facilitate versatile reactions, making it a staple in high-volume sectors:
- Plasticizers: Core raw material for di-octyl phthalate (DOP) and other phthalates, enhancing flexibility in PVC for wires, flooring, and automotive interiors, accounting for over 70% of global PA consumption.
- Resins and Coatings: Reacts with glycols to form alkyd resins for paints, varnishes, and enamels, providing gloss, adhesion, and weather resistance.
- Unsaturated Polyesters: Polymerized with styrene for fiberglass composites in boats, automotive parts, and construction, offering lightweight strength and corrosion resistance.
- Dyes and Pigments: Used in anthraquinone dye synthesis for textiles and inks, delivering vibrant, fade-resistant colors.
- Pharmaceuticals and Agrochemicals: Serves as an intermediate for phthalimide-based herbicides and drug precursors, supporting precision agriculture and healthcare.
- Sustainable Alternatives: Increasingly incorporated into bio-based polyesters and low-VOC coatings, aligning with phthalate-free trends and circular plastics.
With annual production exceeding 5 million tons worldwide, phthalic anhydride drives innovations in durable, eco-efficient materials.
Why Choose Aozun Chem’s Phthalic Anhydride?
- Superior Quality: Adheres to ISO 9001 and REACH standards, with <0.1% free acid content for reduced side reactions and superior ester yields.
- Competitive Economics: Bulk pricing optimized for volume buyers, with flexible terms for stable supply.
- Worldwide Reach: Reliable logistics to Asia, Europe, and North America, with MOQs from 1 MT.
- Expert Partnership: Tailored technical support, including reaction kinetics analysis and impurity profiling.
- Sustainability Integration: Low-emission processes and compatibility with recycled feedstocks, compliant with EU REACH and EPA VOC limits.
Trust Aozun Chem’s phthalic anhydride to elevate your manufacturing precision and environmental footprint.
Frequently Asked Questions (FAQs)
What is phthalic anhydride, and what makes it essential in the plastics industry?
Phthalic anhydride (C₆H₄(CO)₂O) is a dehydrated form of phthalic acid, crucial for producing phthalate esters that plasticize PVC, improving flexibility and processability. Its high reactivity and cost-effectiveness make it indispensable, with over 4 million tons used annually in flexible packaging and consumer goods.
How is phthalic anhydride produced?
It is chiefly manufactured by air oxidation of o-xylene over vanadium catalysts at 350-400°C, followed by distillation. This fixed-bed process achieves 90%+ yields and is preferred over older naphthalene routes for lower emissions and higher efficiency.
What safety protocols are required for handling phthalic anhydride?
As a skin and respiratory irritant (may cause allergic dermatitis), use PPE including gloves and respirators. It sublimes at 131°C, so store in cool (<40°C), dry conditions away from water to prevent hydrolysis. Non-flammable but combustible dust; LD50 oral >10,000 mg/kg in rats.
Is phthalic anhydride suitable for food-contact or medical applications?
In polymerized forms like PET or alkyds, derivatives comply with FDA 21 CFR 175.300 for indirect food contact. Direct use is limited due to migration risks, but purified grades support medical-grade resins when meeting USP Class VI standards.
What is the shelf life and storage recommendation for phthalic anhydride?
Stable for 12-24 months in sealed, moisture-barrier packaging at <30°C to avoid fusion or degradation. Monitor for color changes indicating oxidation; nitrogen blanketing extends usability in humid environments.
Can phthalic anhydride be used in eco-friendly or bio-based formulations?
Yes, it pairs with bio-alcohols for renewable plasticizers like di-2-propylheptyl phthalate, reducing petroleum dependency by 30-50%. It’s also key in recyclable unsaturated polyesters for wind turbine blades, advancing net-zero manufacturing.
How does phthalic anhydride compare to maleic anhydride in resin production?
Phthalic anhydride yields rigid, aromatic structures for durable alkyds and polyesters, while maleic anhydride (unsaturated) enables faster curing in composites. PA dominates volume applications (80% market share) for its stability, versus maleic’s role in high-performance, cross-linked systems.
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