Trioctyl Trimellitate (TOTM) – CAS No. 3319-31-1

Product Overview

Trioctyl Trimellitate (TOTM), chemically known as tris(2-ethylhexyl) trimellitate with the formula C₃₃H₅₄O₆ and CAS Number 3319-31-1, is a high-molecular-weight, branched alkyl trimellitate ester serving as a premium plasticizer for polyvinyl chloride (PVC) and other polymers. This pale yellow, oily liquid exhibits low volatility, exceptional thermal stability up to 200°C, and excellent electrical insulation properties, making it ideal for demanding applications requiring long-term flexibility and resistance to extraction by oils or solvents. With a purity ≥99%, TOTM provides superior migration resistance and low-temperature pliability, outperforming general-purpose phthalates in high-heat environments while maintaining clarity and non-toxicity. Its high solvency ensures efficient processing, and its compliance with food-contact regulations supports use in sensitive end-products without compromising performance or safety.

Key benefits of Trioctyl Trimellitate include:

  • Low Volatility: Minimal weight loss at elevated temperatures, extending service life in wire insulation and automotive components.
  • Thermal Endurance: Retains flexibility after prolonged heat aging, suitable for 105°C-rated cables.
  • Electrical Insulation: High dielectric strength for non-halogenated wire and cable jacketing.
  • Extraction Resistance: Withstands oils, fuels, and solvents, reducing softening in flexible PVC.
  • Regulatory Compliance: FDA-approved for food-contact (21 CFR 175.300), with low toxicity and no phthalate concerns.

TOTM is synthesized through esterification of trimellitic anhydride with 2-ethylhexanol, yielding a robust plasticizer that meets ASTM and ISO standards for polymer additives.

Item Quality index
Appearance transparent liquid
Color (Pt-Co) ≤ 40(Superior≤30)
Acid value, mgKOH/g ≤ 0.10
Water content, wt% ≤ 0.05
Heating loss(125℃×3hrs),wt%≤ 0.1
Density (20℃), g/cm³ 0.984-0.991
Flash point,℃ ≥ 245
Volume resistivity(20℃), (Ω.cm)×1011 ≥ 10
Ester content, wt%≥ 99.5
2-Ethyl hexanol, ppm ≤ 500(Superior≤100)
DOP/DEPH, ppm≤ 100(Superior≤50)
DOTP/% ≤ 0.6
These specifications position TOTM as a top-tier plasticizer for precision PVC compounding and extrusion processes.

Applications-Trioctyl trimellitate

Wire and Cable

  • Insulation and Jacketing: Incorporated at 40-60 phr in PVC compounds for low-voltage cables, providing flame retardancy and flexibility at -40°C to 105°C.
  • Automotive Wiring: Enhances heat resistance in harnesses and under-hood applications, meeting UL 1581 standards.

Flexible PVC Products

  • Automotive Interiors: Plasticizer at 30-50 phr for dashboards and seals, offering UV stability and low fogging.
  • Medical Tubing: Used in non-DEHP formulations for blood bags and IV lines, ensuring biocompatibility and extractables compliance.

Other Industrial Uses

  • Film and Sheeting: 35-55 phr in agricultural films and tarpaulins for weather resistance and durability.
  • Food Packaging: Compliant additive in flexible films for indirect contact, maintaining integrity under thermal stress.

Why Choose Our Trioctyl trimellitate?

Our Trioctyl Trimellitate is distilled to acid value <0.05 mg KOH/g and color <50 APHA, with undetectable free alcohols (<0.1%) for unmatched purity and processing ease. Cable manufacturers achieve 25% better migration resistance and extended flex life in UL-tested compounds. Available in technical and food-grade variants, packaged in 200kg drums, 1000kg IBCs, or bulk tankers, with customizable viscosity and full REACH/FDA certifications for global compliance.

Frequently Asked Questions (FAQs)-Trioctyl trimellitate(TOTM)

What is Trioctyl Trimellitate (TOTM)?

Trioctyl Trimellitate (TOTM) is a trimellitate plasticizer with formula C₃₃H₅₄O₆ and CAS 3319-31-1, designed for PVC to impart low volatility and high-temperature flexibility. It’s a pale yellow liquid used in cables, films, and medical applications.

How is Trioctyl trimellitate(TOTM) used in PVC wire insulation?

Blend at 45-55 phr with PVC resin and stabilizers during compounding; it ensures low smoke generation and maintains elongation >200% after 7-day heat aging at 100°C.

Is TOTM safe for food-contact materials?

Yes, TOTM is FDA-approved under 21 CFR 178.3740 for repeated-use articles, with migration limits <0.5 mg/in², making it suitable for packaging without health risks.

What is the shelf life of TOTM?

Stored in sealed containers below 40°C away from oxidizers, TOTM remains stable for 24-36 months, with no significant ester hydrolysis or viscosity change.

Can TOTM replace DOP in high-heat applications?

TOTM excels over DOP with 50% lower volatility and better extraction resistance; it’s ideal for 90°C+ uses but requires higher gelation temperatures—test in pilot extrusions.

Does TOTM affect PVC processing temperatures?

TOTM’s high solvency allows processing at 160-180°C, reducing fusion time by 10-15% compared to linear phthalates while preserving clarity.

What packaging options are available for TOTM?

We offer 220kg steel drums, 1000kg HDPE IBCs, and 20MT isotanks, all nitrogen-flushed for stability and compliant with UN 3082 for international shipment.

For compounding recipes, compliance data, or volume quotes, our plasticizer experts provide personalized support.

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